Product Identification
【Product Name】Methyl anisate 　对甲氧基苯甲酸甲酯
【Synonyms】4-(Methoxycarbonyl)anisole
【CAS】121-98-2
【Formula】C9H10O3
【Molecular Weight】166.17
【EINECS】204-513-2
【RTECS】BZ4925000
【RTECS Class】Natural Product; Primary Irritant
【Beilstein/Gmelin】2208571
【Beilstein Reference】4-10-00-00360

Physical ａnd Chemical Properties
【Appearance】White powder.
【Solubility in water】Insoluble
【Melting Point】48
【Boiling Point】256
【Vapor Pressure】0.016 (25 C)
【Partition Coefficient】2.27
【Heat Of Vaporization】49.4 kJ/mol
【Heat Of Combustion】-4477 kJ/mol

First Aid Measures
【Ingestion】If victim is conscious ａnd alert, give 2-4 cupfuls of milk or water. Get medical aid immediately.
【Inhalation】Get medical aid immediately. Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen.
【Skin】Get medical aid. Flush skin with plenty of soap ａnd water for at least 15 minutes while removing contaminated clothing ａnd shoes. Wash clothing before reuse.
【Eyes】Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper ａnd lower eyelids. Get medical aid immediately.

Handling ａnd Storage
【Storage】

Keep container closed when not in use. Store in a cool, dry, well-ventilated area away from incompatible substances.
【Handling】Wash thoroughly after handling. Remove contaminated clothing ａnd wash before reuse. Avoid contact with eyes, skin, ａnd clothing. Avoid ingestion ａnd inhalation.

Hazards Identification
【Ingestion】May cause gastrointestinal irritation with nausea, vomiting ａnd diarrhea.
【Inhalation】May cause respiratory tract irritation.
【Skin】May cause skin irritation.
【Eyes】May cause eye irritation.
【Hazards】Vapors may form explosive mixtures with air. Vapors may travel to source of ignition ａnd flash back. Most vapors are heavier than air. They will spread along ground ａnd collect in low or confined areas (sewers, basements, tanks). Vapor explosion hazard indoors, outdoors or in sewers.
【EC Safety Phrase】S 22 24/25
【UN (DOT)】2319

Exposure Controls/Personal Protection
【Personal Protection】Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA＇s eye ａnd face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure.
【Respirators】Follow the OSHA respirator regulations found in 29CFR 1910.134 or European Standard EN 149. Always use a NIOSH or European Standard EN 149 approved respirator when necessary.

Fire Fighting Measures
【Flash Point】

98
【Fire Fighting】Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), ａnd full protective gear. During a fire, irritating ａnd highly toxic gases may be generated by thermal decomposition or combustion. Extinguishing media: Use agent most appropriate to extinguish fire. In case of fire use water spray, dry chemical, carbon dioxide, or appropriate foam.
【Fire Potential】HIGHLY FLAMMABLE: Will be easily ignited by heat, sparks or flames.

Accidental Release Measures
【Small spills/leaks】Clean up spills immediately, using the appropriate protective equipment. Sweep up or absorb material, then place into a suitable clean, dry, closed container for disposal. Avoid generating dusty conditions. Provide ventilation.

Stability ａnd Reactivity
【Stability】Stable under normal temperatures ａnd pressures.
【Incompatibilities】Strong oxidizing agents.
【Decomposition】Irritating ａnd toxic fumes ａnd gases.
【Combustion Products】Fire may produce irritating, corrosive and/or toxic gases.

Transport Information
【UN Number】2319
【Hazard Class】3
【Packing Group】III