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深圳市和华利贸易有限公司 手机:13620934101,手机:屏蔽谭丽
1. Identification of the product and the company
Trade name : GulfSea PE Cooloil. (ISO VG 32, 46, 68, 100, 150 & 220)
Use : Refrigeration Compressor Lubricant
Company identification : Gulf Oil Marine Ltd. 13th Floor, Fortis Tower, No. 77-79 Gloucester Road,
Wan Chai, Hong Kong
Tel : (852) 3693 0568 Fax : (852) 3748 9960 www.gulf-marine.com
Emergency phone nr : Tel : (852) 3693 0568
Company : As above.
2. Information on ingredients
This product is not considered to be hazardous and does not contain hazardous components.
Composition (preparation) : Blend of Synthetic base stocks (Carboxylic Esters)
Substance name Value (s) CAS nr EINECS nr EC index CERTIFCATE
Polyol Ester : 80 - 100 % MIXTURE ------ ----- -----
3. Hazards identification
4. First aid measures
First aid
- Inhalation : Assure fresh air breathing. Obtain medical attention if breathing difficulty
persists.
- Skin contact : Remove affected clothing and wash all exposed skin area with mild soap
and water, followed by warm water rinse. Wash skin thoroughly with mild
soap and water. Seek medical attention if irritation develops.
- Eye contact : Rinse immediately with plenty of water. Seek medical attention if irritation
develops.
- Ingestion : DO NOT INDUCE VOMITING. Seek medical attention immediately.
General information : Treat symptomatically. If there is any suspicion of aspiration into the
Main hazards : Not a dangerous preparation according to 1999/45/EC.
Adverse human health effects : None under normal conditions.
Environmental hazards : No specific risk for the environment.
Symptoms relating to use
Inhalation : Not expected to present a significant inhalation hazard under anticipated
conditions of normal use. Symptoms of overexposure to vapours include
drowsiness, weakness, headache, dizziness, nausea, vomiting, dimming of
vision.
Skin contact : Not expected to present a significant skin hazard under anticipated
conditions of normal use. Prolonged or repeated contact may cause skin
to become dry or cracked.
Eye contact : Not expected to present a significant eye contact hazard under
anticipated conditions of normal use. Direct contact with the eyes is
likely slightly irritating.
Ingestion : Not expected to present a significant ingestion hazard under anticipated
conditions of normal use.
Note : Used oils can get contaminated with refrigerant gases, some of which
may be hazardous. Please see Section 13 of this MSDS
Product name: GulfSea PE Cooloil Page: 2/5
Revision Date: 14/02/2017 Revision nr: 4
Product No.: 2SR1000 Supersedes: 25/07/14
MATERIAL SAFETY DATA SHEET
lungs either directly or as a result of vomiting, obtain medical advice.
5. Fire - fighting measures
Extinguishing media
Suitable extinguishers : Water fog. Carbon dioxide. Dry chemical. Foam. Sand.
Extinguishers not to be used : Do not use a heavy water stream.
Surrounding fires : Use water spray or fog for cooling exposed containers.
Special exposure hazards : Regular/ proper maintenance of compressors is essential as they may
otherwise lead to a potential fire and explosion hazard. See also
hazardous reactions § 10.
Protection against fire : Do not enter fire area without proper protective equipment, including
respiratory protection.
Special procedures : None Identified.
6. Accidental release measures
Personal precautions : Avoid all unnecessary exposure. Keep public away from danger area.
Wear recommended personal protective equipment. Equip cleanup
crew with proper protection.
Environmental precautions : Prevent entry to sewers and public waters. Notify authorities if liquid
enters sewers or public waters.
After spillage and/or leakage : Clean up any spills as soon as possible, using an absorbent material to
collect it. Collect spills and put it into appropriated container. Use suitable
disposal containers. Recover the cleaning water for disposal. Spill area
may be slippery.
on soil : May require excavation of contaminated soil.
7. Handling and storage
General : No naked lights. No smoking. Keep away from sources of
ignition. Avoid all unnecessary exposure.
Precautions in handling and
storage
: Handle in accordance with good industrial hygiene and safety
procedures.
Storage : Keep container closed when not in use. Keep only in the original
container in a cool, well ventilated place. Keep at temperature not
exceeding 45°C.
Handling : Wash hands and other exposed areas with mild soap and water
before eat, drink or smoke and when leaving work. Ensure prompt
removal from eyes, skin and clothing.
Product name: GulfSea PE Cooloil Page: 3/5
Revision Date: 14/02/2017 Revision nr: 4
Product No.: 2SR1000 Supersedes: 25/07/14
MATERIAL SAFETY DATA SHEET
8. Exposure controls / personal protection
Personal protection
- Respiratory protection : No special respiratory protection equipment is recommended under
normal conditions of use with adequate ventilation. Where excessive
vapour may result, wear approved mask.
- Hand protection : Use neoprene or rubber gloves.
- Skin protection : No special clothing/skin protection equipment is recommended under
normal conditions of use. In case of possible repeated skin contact wear
protective clothing.
- Eye protection : Safety glasses.
Industrial hygiene : Provide local exhaust or general room ventilation to minimize dust
and/or vapour concentrations. When using, do not eat, drink or smoke.
Emergency eye wash fountains and safety showers should be available
in the immediate vicinity of any potential exposure.
Occupational Exposure Limits : according to TWA (TLV) ACGIH : 3 mg/m³ for oil mist.
9. Physical and chemical properties
Physical state : Liquid.
Colour : Colourless to light yellow.
Odour : Ester.
Pour point [°C] : < -28
Initial boiling point [°C] : > 200
Viscosity at 40°C [mm²/s] : 32 to 220
Solubility in water : Insoluble.
Flash point [°C] (ASTM D 92) : > 240
Specific gravity : 0.96 to 0.99
10. Stability and reactivity
Physico-chemical stability : Stable.
Conditions to avoid : Open flame. Sparks. Overheating.
Materials to avoid : Oxidizing agents.
Hazardous decomposition
products
: Carbon dioxide. Carbon monoxide.
Hazardous reactions : None under normal conditions
Hazardous Polymerization : Will not occur.
Product name: GulfSea PE Cooloil Page: 4/5
Revision Date: 14/02/2017 Revision nr: 4
Product No.: 2SR1000 Supersedes: 25/07/14
MATERIAL SAFETY DATA SHEET
11. Toxicological information
Acute toxicity : Not expected to be toxic.
- Inhalation : Practically non toxic at normal conditions of usage. May cause
respiratory irritation following prolonged or repeated inhalation of
excessive oil mist and vapours.
- Dermal : Not expected to be a primary skin irritant. Prolonged or repeated exposure
may lead to dermatitis. LD50 rat > 2000mg/kg
- Ocular : Repeated exposure may cause a slight irritation.
- Ingestion
: Practically non toxic if swallowed in small doses. Larger quantities
may cause nausea & diarrhoea. LD50 rat > 5000 mg/kg
- Chronic toxicity : Not expected to be toxic.
- Sensitization : No sensitization effects known.
- Carcinogenicity : No data available. The ingredients used in this preparation are not
associated with carcinogenic effects.
- Mutagenicity : Not expected to be a mutagenic hazard.
12. Ecological information
Ecological effects information : Adverse effects to the environment are not expected from this product
LC50-96 Hour - fish [mg/l]
: >100
48 Hour-EC50 - Daphnia magna
[mg/l]
: >100
Persistence and degradability : Readily Bio-degradable. >70% degradation within 28 days according to
modified Sturm test.
Bioaccumulative potential : Not determined.
Mobility soil : Ground water contamination may be caused through spillages
13. Disposal considerations
Disposal : Dispose in a safe manner in accordance with local/national regulations.
Used Oils- Used oils contaminated with refrigerant gases which are
hazardous may require specific disposal precautions. The MSDS of the
gas concerned can be referred to for details in this regard.
Waste-disposal procedures : Dispose in a safe manner in accordance with local/national regulations.
Dispose only by approved contractors following regulations
covering disposal of halogenated materials. If Permitted - Burn in a
chemical incinerator equipped with an afterburner and a scrubber.
Attention : national and/or local laws and regulations may preclude
14. Transport information
General information : The product is not covered by international regulations on the transport of
dangerous goods (IMDG, IATA, ADR/RID).
UN No. : Not regulated.
ADR/RID : Not regulated.
IMO-IMDG code : Not regulated.
ICAO/IATA : Not regulated.
Product name: GulfSea PE Cooloil Page: 5/5
Revision Date: 14/02/2017 Revision nr: 4
Product No.: 2SR1000 Supersedes: 25/07/14
MATERIAL SAFETY DATA SHEET
15. Regulatory information
EC Labelling : Not classified.
Symbol(s)
: None.
R Phrase(s)
: None.
S Phrase(s)
: None.
Regul./ EINECS : All components are in compliance with the EC Seventh amendment
Directive 92/32/ EEC
Canada : In compliance ( DSL )
SARA – USA : Section 311 and 312 hazards classification(s) : None
US Toxic Substances Control Act
- TSCA
: In compliance
Australian Inventory of Chemical
Substances (AICS)
: In compliance
WHMIS (Canada)
: Not classified. Not listed on the Canadian Controlled Product Ingredient
Disclosure and is compliant with Controlled Products Regulation.
OSHA hazardous chemical(s) : Not classified as hazardous in accordance with OSHA 29 CFR 1910.1200.
16. Other information
Further information :
For specific or detailed technical data for this product, please contact
your local sales representative.
The contents and format of this MSDS are in accordance with Regulation (EC) Np 1907/2006 of the European
Parliament and of the Council.
DISCLAIMER OF LIABILITY
The information in this MSDS was obtained from sources which we believe are reliable. However, the information
is provided without any warranty, express or implied, regarding its correctness. The conditions or methods of
handling, storage, use or disposal of the product are beyond our control and may be beyond our knowledge. For
this and other reasons, we do not assume responsibility and expressly disclaim liability for loss, damage or
expense arising out of or in any way connected with the handling, storage, use or disposal of the product. This
MSDS was prepared and is to be used only for this product. If the product is used as a component in another
product, this MSDS information may not be applicable.
End of document