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分子式:C9H17NO
分子量:155.24
中文名称: 四甲基哌啶酮
2,2,6,6-四甲基-4-哌啶酮
2,2,6,6-四甲基哌啶酮
三丙酮胺
TAA
英文名称: 2,2,6,6-tetramethyl-4-Piperidi
2,2,6,6-tetramethyl-4-piperidone
2,2,6,6-tetramethyl-4-piperidi
2,2,6,6-tetramethyl-4-piperidone
2,2,6,6-tetramethylpiperidi
三丙酮胺性状描述: 该品为白色或淡黄色粉末,熔点43℃,沸点205℃,比重0.92g/cm3,闪点92℃,能溶于丙酮,醇,醚和水。三丙酮胺本身的稳定性不好,一般在有空气存在下放置3~4天后,就会由原来的乳白色变为淡黄色甚至棕红色。放置时间越长,物料颜色越深。
三丙酮胺质量标准:
外观 浅黄色至棕红色熔融体
纯度 ≥97.0%(GC)
灰分 ≤0.10%
水分 ≤1.20%
三丙酮胺用途: 主要作为合成受阻胺类光稳定剂的母体。经它还原制得的2,2,6,6-四甲基-r-哌啶醇是制取新型高效光稳定剂770、GW-540(cas95733-09-8 [亚磷酸三(1,2,2,6,6-五甲基哌啶醇)酯])和HALS的重要原料,同时也是制取4-取代硫基-2,2,6,6-四甲基哌啶氨氧自由基化合物的重要中间体。
三丙酮胺Product Identification
【Product Name】2,2,6,6-Tetramethyl-4-piperidone
【Synonyms】Triacetonamin;2,2,6,6-四甲基哌啶酮
【CAS】826-36-8
【Formula】C9H17NO
【Molecular Weight】155.27000000000001
【EINECS】212-554-2
【RTECS】TO0127900
【RTECS Class】Drug
【Beilstein/Gmelin】112665
【Beilstein Reference】5-21-06-00538
三丙酮胺Physical and Chemical Properties
【Appearance】White - beige powder
【Solubility in water】Very soluble
【Melting Point】62℃
【Boiling Point】206℃
【Vapor Pressure】0.25 (25℃)
【pKa/pKb】4.80 (pKa)
【Refractive Index】1.463 (20℃)
三丙酮胺First Aid Measures
【Ingestion】If victim is conscious and alert, give 2-4 cupfuls of milk or water. Get medical aid.
【Inhalation】Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen.
【Skin】Get medical aid. Flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes.
【Eyes】Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower lids. Get medical aid immediately.
三丙酮胺Handling and Storage
【Storage】Keep container closed when not in use. Refrigerator (approx 4 C).
【Handling】Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Avoid contact with eyes, skin, and clothing. Avoid ingestion and inhalation.
Hazards Identification
【Ingestion】Harmful if swallowed.
【Inhalation】May cause respiratory tract irritation.
【Skin】May cause skin irritation.
【Eyes】May cause eye irritation.
Fire Fighting Measures
【Flash Point】73℃
【Fire Fighting】Wear approved SCBA in full pressure-demand and full protective gear. Use agent most appropriate to extinguish fire.
Exposure Controls/Personal Protection
【Respirators】A respiratory protection program that meets OSHA's 29 CFR ß1910.134 and ANSI Z88.2 requirements or European Standard EN 149 must be followed whenever workplace conditions warrant a respirator's use.
三丙酮胺Accidental Release Measures
【Small spills/leaks】Clean up spills immediately, while using/wearing the proper protective equipment.
Stability and Reactivity 99% 25L/桶 98% 30kg/桶 99% 25kg/桶 99% 25kg/桶 95% 25kg/桶 99% 1kg/包 98% 25kg/桶
【Stability】Stable under normal temperatures and pressures.
【Incompatibilities】Strong oxidizing agents.
【Decomposition】Carbon monoxide, carbon dioxide.
品名 CAS号 规格 包装 法尼基丙酮 1117-52-8 丙酮酸 127-17-3 三氟丙酮酸乙酯 13081-18-0 三甲基丙酮酸 815-17-8 二乙酰丙酮镍 3264-82-2 3-吲哚丙酮酸 392-12-1 邻硝基苯丙酮酸 5461-32-5